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RoHS detection solution
Category : Solution1
Release time: 2014-03-18 16:47
RoHS is a mandatory standard developed by EU legislation, and its full name is the Restriction of Hazardous Substances in Electrical and Electronic Equipment. This standard has been officially implemented on July 2006, 7, mainly used to standardize the material and process standards of electronic and electrical products, making them more conducive to human health and environmental protection. The purpose of the standard is to eliminate lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls and polybrominated diphenyl ethers from electrical and electronic products, and emphasizes that the lead content should not exceed 1.6%. New Directive 0/1/EU (RoHS 2011.65) to replace 2/0/EC (RoHS) The new Directive will enter into force on 2002 July 95. In terms of comparing RoHS 2011.7 to RoHS, the main changes are as follows:
1. Appendix I and IA of the original WEEE Directive are added as two Appendices to RoHS.
2. From January 2014, 1 to January 1, 2017, gradually bring medical equipment and monitoring equipment into the scope of RoHS control.
3. Manufacturers need to formulate EC declaration of conformity and affix CE marking before the product is put on the market, and after the electronic and electrical products are on the market, they must retain relevant technical documents and EC declaration of conformity for at least ten years.
4. If the substances listed in Annex III (such as HBCDD, DEHP, BBP and DBP, etc.) cause unacceptable harm to human health or the environment due to use, they will be assessed in accordance with the provisions of Articles 69 to 72 of the REACH Regulation and further listed as restricted substances in Annex IV. The main test substances in the RoHS requirements are as follows:
Restricted substances |
Limit content |
Mercury (Hg) |
100ppm |
Hexavalent chromium (Cr VI) |
1000ppm |
Cadmium (Cd) |
100ppm |
Lead (Pb) |
1000ppm |
Polybrominated biphenyls (PBBs) |
1000ppm |
Polybrominated diphenyl ethers (PBDEs) |
1000ppm |
"Detection Methods for Toxic and Harmful Substances in Electronic Information Products" (hereinafter referred to as "Test Methods", standard number SJ/T 11365-2006) limits the test methods for hazardous elements in RoHS requirements. Among them, X-ray fluorescence spectroscopy (XRF) has been formulated as a rapid screening method as the fastest and most convenient method. X-ray fluorescence spectroscopy (XRF) enables precise testing of standard samples for five elements: lead (Pb), mercury (Hg), cadmium (Cd), chromium (Cr) and bromine (Br). However, the results obtained based on the principle of XRF are only the content of the elements, that is, if the content of chromium (Cr) or bromine (Br) obtained by this screening test, even if they exceed the standard, it does not represent that the hazardous substance (Cr VI) and the flame retardants PBB and PBDE) exceed the standard, and this test result (refers to the content) is only a necessary condition for containing the corresponding harmful substance but not a sufficient condition. This is why there is no basis for judging the unqualified limit values of these two hazardous substances in the limit value table.
RoHS is applicable to industries
1. Large household appliances:
Large refrigeration appliances, refrigerators, freezers, and other large appliances for food refrigeration, preservation and storage.
2. Small household appliances:
Vacuum cleaners, carpet sweepers, other cleaning utensils, utensils for sewing, weaving and other fabric processing, etc.
Information and communication equipment:
Central data processor, personal computer, printer, copy equipment, electrical and electronic typewriter, desktop and pocket calculator, etc.
4. Consumer Products:
Radios, televisions, video recorders, tape recorders, high-fidelity tape recorders, amplifiers, musical instruments, and other products or equipment that record or reproduce sound and images.
5. Lighting equipment:
Fluorescent lamps (except household lighting equipment), straight fluorescent lamps, compact fluorescent lamps, high-brightness discharge lamps, etc.
6. Electrical and electronic tools:
Electric drills, chainsaws, sewing machines, turning, milling, sanding, grinding, sawing, cutting, shearing, drilling, punching, folding, bending or other materials of wood, metal or other materials
Equipment similar to processing, etc.
7. Toys, leisure and sports equipment:
Electric trains or racing cars, handheld electronic game consoles, electronic game consoles, measuring devices for cycling, diving, running, boating, etc.; Sports equipment with electronic or electrical components.
8. Medical equipment (except implanted or infected products):
Radiotherapy equipment, cardiac equipment, fluoroscopy devices, lung ventilators, nuclear medical equipment, etc.
9. Monitoring and control instruments:
Smoke detectors, heat regulators, thermostats, measuring, weighing or adjusting appliances for household or laboratory equipment, other monitoring instruments used in industrial installations (e.g. on control panels).
10. Vending machines:
Hot drink vending machines, bottled or canned hot or cold beverage vending machines, solid product vending machines, money ticket vending machines, all automatic delivery of various products.
Note: At present, Class VIII and IX medical equipment, monitoring and control instruments are not subject to the RoHS directive, but medical equipment and monitoring equipment and their parts should meet the requirements of RoHS 2014.7 standards from July 22, 2.
List of hazardous substance uses:
First, the main use of cadmium
name |
Main uses |
cadmium |
Connection material, surface treatment (electroplating), nickel-cadmium battery |
Cadmium alloys |
Low melting point welding, fuse |
Cadmium oxide |
Pigments, alkaline batteries, chemical synthetic materials |
Cadmium chloride |
Plating bath, stabilizer of polyvinyl chloride (PVC). |
Cadmium sulfide |
Pigments, semiconductor light-receiving elements, paints, inks |
Cadmium nitrate, cadmium nitrate tetrahydrate |
Colorants for glass and ceramics, emulsifiers for photographic films, and analytical reagents, It is also used in the manufacture of other cadmium salts and cadmium oxide, catalysts, batteries and cadmium-containing agents. |
Cadmium sulfate |
Nickel-cadmium batteries |
Cadmium stearate |
Ripe and light-resistant transparent stabilizer for polyvinyl chloride (PVC) plastics, Smoothing agent and transparent softener for high-grade rubber products and films |
Second, the main use of lead
name |
Main uses |
Lead, metallic lead |
Plumb hammer, lead-acid battery |
Lead-tin alloy |
Welding, waxing materials, electrical connections |
Lead oxide (divalent) |
Pigments, rubber vulcanizing agents, solid lubricants |
Lead oxide (quadrivalent) |
Lead-acid batteries, rubber curing agents, pigment raw materials |
Lead trioxide |
Pigment raw materials |
Lead tetroxide |
Pigments, lead-acid batteries, glass, coatings |
Lead fluoride |
Special optical glass, pigments |
Lead iodide |
Bronze, print, photo |
Lead sulfide |
Semiconductor UV detector |
Lead cyanide |
Anti-rust pigments |
Boron lead fluoride |
Plating solution, corrosion-resistant surface treatment |
Lead silicon fluoride |
Plating solution, lead refining |
Lead nitrate |
Optical |
Lead hydroxide carbide, lead carbonate |
Pigments, PVC stabilizers |
Lead sulfate (divalent) |
Pigments, rubber compounds, PVC stabilizers, lead-acid batteries |
Lead carbonate |
Glaze, paint pigments (oil painting, watercolor), medicine (hard paste), vinyl chloride stabilizer, glue |
Lead sulfate |
pigment |
name |
Main uses |
Lead phosphate (divalent) |
pigment |
Lead thiocyanate |
Dyes, matches |
Lead oleate |
Lubricants, hardeners |
Lead stearate |
Translucent heat-resistant stabilizer for plastics such as PVC, thickener for lubricants |
Lead metaborate (divalent) |
Desiccant for paint |
Lead silicate |
ceramics |
Lead antimonite |
Pigments, glass coloring |
Lead arsenite, lead arsenate |
insecticide |
Lead chlorate, chrome yellow |
Pigments, paints, inks |
Lead molybdate |
pigment |
Calcium leadate |
oxidant |
Salt-based lead sulfate |
Stabilizer for plastics such as PVC (mainly excellent heat resistance, electrical insulation and light resistance) |
Lead hydrostearate |
Heat stabilizer for plastics such as PVC |
Lead chloride (bivalent and tetravalent) |
Used as a reagent to manufacture other lead salts and lead chromate pigments |
Tetramethyl lead, tetraethyl lead |
Gasoline antiknock agent, increase octane rating |
Lead acetate (bivalent and tetravalent) |
Lead salt manufacturing raw materials, polymerization catalyst, dyeing workshop measuring agent, organic synthesis selective oxidant, traditional Chinese medicine |
Third, the main uses of mercury
name |
Main uses |
mercury |
Widely used in electrical instrument industry, manufacturing mercury rectifier equipment, mercury vacuum pumps, measurement, control instruments. In the lighting industry, mercury is used in the manufacture of various mercury lamps, fluorescent lamps, and ultraviolet lamps. Medical thermometers. electrode |
amalgam |
Titanium amalgam: widely used in various fluorescent lamps and tubes, silver amalgam: dental medical supplies |
amalgam |
Electronic energy-saving lamps, fluorescent lamps, zinc amalgam: are alkaline, high-performance electromercury negative active materials. In addition to being used as a power supply material for military and space, it is also the main base material for the current power supply of miniature electronic appliances. |
mercuric oxide |
Yellow: Manufacture of organic mercury compounds; Red: Manufacture of mercury batteries, organic reaction catalysts |
Mercuric dichloride (monovalent) |
(calomel) electrodes, pigments |
Mercuric chloride (divalent) |
Metal etching, preservatives, catalysts for chlorine-dilute synthesis, dry cell depolarizers, disinfectants, tablet washing, development, Thickening agent and other mercury salt raw materials. |
Mercuric nitrate (divalent) |
Linoleum, catalysts, veterinary drugs, insecticides |
mercuric sulfide |
Also known as "cinnabar".A large number of proprietary Chinese medicines, in line with the requirements of the National Pharmacopoeia as a sedative anti-inflammatory drug for the nervous system, It has a history of thousands of years in China, and is used in industry as bright red pigments and advanced drawing pigments for paint, printing clay, rubber, etc. The color is bright and never fades, which is incomparable to other red pigments. In addition to its bright color, granular cinnabar is also crystalline, making it a good material for ornaments. |
Mercury iodide |
Pharmaceutical |
Thunder mercury (bivalent) |
gunpowder |
Mercuric acetate (divalent) |
Veterinary drugs, insecticides |
Methylmercury salt |
Antifungal agent |
Ethalkyl mercury salt |
Antifungal agent, fungicide |
Aminomercuric chloride |
Pharmaceutical |
Propylmercury salt |
insecticide |
Phenylmercury salts |
Preservatives, fungicides |
Methyloxyethane mercury salt |
Antifungal agent, fungicide |
Dihydrocarbon group mercury |
Antifungal agent |
Diphenylmercury |
Antifungal agent |
Mercuric sulfate (monovalent) |
Battery, used with sodium chloride, extracts gold and silver from chalcopyrite, and determines barbiturates and cystine. |
Fourth, hexavalent chromium - main uses
name |
Main uses |
Chromium trioxide, chromium oxide (hexavalent), chromium anhydride |
Pigments, catalysts, electroplating, tanned leather |
Lithium chromate |
preservative |
Sodium chromate |
Anti-rust, tanned |
Potassium chromate |
Pigments, inks, tanned leather |
Ammonium chromate |
Photo, catalyst |
Copper chromate |
Mordant |
Magnesium chromate |
Anti-rust, surface treatment |
Calcium chromate |
Pigments, inks, tanning |
Strontium chromate |
Pigments, rust proof |
Barium chromate |
Pigments, anticorrosion, ceramic colorants |
Lead chromate, chrome yellow |
Pigments, coatings, inks |
Zinc chromate |
Pigments, preservatives |
Sodium dichromate |
Pigments, embalming, photos, tanning |
Ammonium dichromate |
Pigments, photographs, catalysts |
Calcium dichromate |
Anticorrosion, catalyst |
Zinc dichromate |
pigment |
potassium dichromate |
Pigments, photographs, plating, batteries, tanning |
More accurate detection results are the unremitting pursuit of Depu people, and Depu people always keep in mind to provide customers with better service. The newly developed IDP-6300 adheres to this concept. It not only inherits the five characteristics of the EDX series of German instruments: accurate, fast, non-destructive, intuitive and environmentally friendly, but also uses the most advanced extreme speed detector technology (X-SDD) in the analytical instrument industry to reduce the test time to 1 second. At the same time, IDP-6300 also adopts the precision positioning system of Depu Instrument's patented product, which can realize image linkage control and multi-point continuous testing. The addition of a newly developed sample chamber makes operation easier, and the newly designed automatic sample platform ensures accurate detection.
Performance benefits
Fast—Results in 1 second
Featuring the industry's most advanced ultra-fast detector technology (X-SDD) with resolutions as low as 125eV
Advantages: large detection area (area up to 25mm2), more information received per unit time, good high resolution of counting rate, higher detection efficiency, stronger detection signal-to-noise ratio, and lower detection limit
Featuring the industry's most advanced digital multichannel technology
Advantages: Effectively improve the output efficiency, achieve ultra-high counting rate, and ensure that the effective counting rate of acquisition can reach up to 1000Wcps
It adopts high-power X-ray tube and advanced collimation filter system
Advantage: Higher excitation efficiency
Optical shutter system
Advantages: Sample exchange does not need to turn off high pressure, improve test efficiency and test accuracy
Sophisticated positioning system
Ultra-high-definition industrial camera, clearer display of test points
Multi-point testing
2D fully automatic mobile sample stage - can realize image linkage control, multi-point continuous testing
Ultra-small sample inspection – down to 0.2 mm
8 kinds of collimators, 4 kinds of filter quick switching function, can be selected according to different samples
Collimators as small as 0.2 mm provide accurate focus detection for ultra-small samples
User-friendly design
Safer: X-ray linkage safety device - optical gate interacts with linkage device; The instrument housing is linked to the high-voltage enable terminal
Faster: multi-point testing, where to measure
Schedule warm-up: According to the set time, the instrument can start the test regularly
Appointment to start up function: customers can make an appointment for the instrument to start up, and at the same time, the instrument can be warmed up and automatically detect and correct the instrument status; At the same time, it can realize the appointment shutdown,
Audible and visual prompts can be set before shutdown
Technical parameters
Measuring element range: sulfur (S) ~ uranium (U)
Measurement time: 1s or more
Detection limit: The detection limit of analysis can reach 2ppm, and the thinnest can be tested up to 0.005μm
Content range: 2ppm~99.9%
Stability: 0.02%
Pipe pressure: 5~50KV
Pipe flow: ≤1000uA
Detector: X-SDD detector with resolution up to 125eV
Collimator: 8 types of collimator automatic switching
Filters: 4 kinds of filters can be switched freely
Sample observation: HD industrial camera
Ambient humidity: ≤70%
Ambient temperature: 15°C~30°C
Power supply: AC 220V±5V (recommended AC purification and stabilized power supply)
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FAQ
Can ROHS testing instruments test metal elements?
ROHS detection instrument is a professional equipment used to detect whether electronic components, household appliances, toys and other products contain harmful substances. These harmful substances may pose a long-term threat to humans and the environment, so the application of ROHS detection instruments is of great significance.
The answer to the question of whether ROHS detection instruments can test metal elements is affirmative. Because the scope of ROHS testing not only includes harmful substances, but also includes the detection of metal element components in qualified products. These metal elements include lead, cadmium, mercury, etc., which are widely used in product manufacturing. Although these elements are necessary, excessive use poses great harm to human health and environmental protection. Therefore, the emergence of ROHS detection instruments has brought great convenience to our detection of metal elements.
Which is the best gas chromatograph?
Gas chromatograph is a commonly used analytical instrument, which is widely used in chemistry, biology, medicine and other fields. However, there are many gas chromatograph brands on the market, and the prices are far from the same, making it difficult to choose. So, which gas chromatograph is better?
First of all, we need to understand the basic principles and performance indicators of gas chromatographs. Gas chromatograph uses samples to evaporate into a gaseous state at high temperatures, separate them by column, and then detect the degree and content of different components by detectors. Common performance metrics include resolution, sensitivity, linear range, repeatability, and more.
When choosing a gas chromatograph brand, we can consider the following aspects:
1. Brand awareness and word of mouth. Well-known brands usually have high technical strength and after-sales service guarantee, and have a better reputation.
2. Technological innovation and R&D capabilities. Gas chromatograph technology is constantly updated, and brands with strong R&D capabilities and technological innovation capabilities are more competitive.
3. Product performance and price. The performance and price of different brands of gas chromatographs vary greatly, and you need to choose according to your actual needs and budget.
4. After-sales service and technical support. Various problems may occur during the use of the gas chromatograph, and after-sales service and technical support can solve the problem in time to ensure that the instrument is running.
Which is the best service provider for RoHS spectrometers?
RoHS spectrometer is an instrument used to detect harmful substances in products. It can detect whether products contain lead, mercury, cadmium, Hexavalent chromium and other harmful substances to ensure human health and environmental safety. So, which one is the best service provider for RoHS spectrometers?
Firstly, we need to understand the basic principles and detection methods of RoHS spectrometers. RoHS spectrometer is an instrument based on the principle of spectral analysis, which can determine whether a sample contains harmful substances by analyzing the elements and compounds in the sample. The detection method of RoHS spectrometer is generally X-ray fluorescence spectroscopy (XRF).
What instruments are used to detect RoHS in electronic and electrical products?
RoHS (Restriction of the Use of Certain Hazardous Substances Directive) is a regulation established by the European Union aimed at limiting the content of harmful substances used in electronic and electrical products. These harmful substances include lead, mercury, cadmium, Hexavalent chromium, polybrominated biphenyls and polybrominated diphenyl ethers. To ensure product compliance with RoHS regulations, specific instruments need to be used for testing.
RoHS testing instrument is a device specifically designed to detect the content of harmful substances in electronic and electrical products. These instruments can detect the content of lead, mercury, cadmium, Hexavalent chromium, polybrominated biphenyls, Polybrominated diphenyl ethers and other harmful substances in products. RoHS test instruments are usually tested with X-ray fluorescence (XRF).
What is ROHS testing?
ROHS testing, full name Restriction of Hazardous Substances testing, refers to the testing of the content of specific hazardous substances in electrical and electronic products and wire and cable products to ensure that the products comply with relevant regulations and standards, thereby protecting consumers and the environment from harmful substances.
The origin of ROHS testing can be traced back to the European Union's Restriction of the Use of Certain Hazardous Substances Directive (RoHS Directive) issued in 2003, which requires companies to limit the content of harmful substances such as lead (Pb), mercury (Hg), cadmium (Cd), hexavalent chromium (Cr6+), polybrominated biphenyls (PBB) and polybrominated diphenyl ethers (PBDE) in electrical and electronic products and wire and cable products sold in the European market, and requires enterprises to test the content of their products.